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Thus, the ratio of the kinetic energy to the absolute temperature of an ideal monatomic gas can be calculated easily: per mole: 12.47 J/K; per molecule: 20.7 yJ/K = 129 μeV/K; At standard temperature (273.15 K), the kinetic energy can also be obtained: per mole: 3406 J; per molecule: 5.65 zJ = 35.2 meV.
Hence, all the energy possessed by the gas is the kinetic energy of the molecules, or atoms, of the gas. = This corresponds to the kinetic energy of n moles of a monoatomic gas having 3 degrees of freedom; x, y, z. The table here below gives this relationship for different amounts of a monoatomic gas.
The other equation of state of an ideal gas must express Joule's second law, that the internal energy of a fixed mass of ideal gas is a function only of its temperature, with = (,). For the present purposes it is convenient to postulate an exemplary version of this law by writing:
Quantity (common name/s) (Common) symbol/s Defining equation SI unit Dimension Temperature gradient: No standard symbol K⋅m −1: ΘL −1: Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer
The total kinetic energy of a system depends on the inertial frame of reference: it is the sum of the total kinetic energy in a center of momentum frame and the kinetic energy the total mass would have if it were concentrated in the center of mass.
Kinetic theory of matter: A general account of the properties of matter, including solids liquids and gases, based around the idea that heat or temperature is a manifestation of atoms and molecules in constant agitation. Kinetic theory of gases, an account of gas properties in terms of motion and interaction of submicroscopic particles in gases
With an instantaneous temperature switch the initial fluid velocity is infinite, resulting in an initial infinite kinetic energy. In fact the liquid layer is often in motion, thus requiring advection or convection terms in the heat equation. The melt temperature may vary with size, curvature or speed of the interface.
This convention means that temperature and energy quantities have the same dimensions. [22] [23] In particular, the SI unit kelvin becomes superfluous, being defined in terms of joules as 1 K = 1.380 649 × 10 −23 J. [24] With this convention, temperature is always given in units of energy, and the Boltzmann constant is not explicitly needed ...