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Iron(II) chloride, also known as ferrous chloride, is the chemical compound of formula FeCl 2. It is a paramagnetic solid with a high melting point. The compound is white, but typical samples are often off-white. FeCl 2 crystallizes from water as the greenish tetrahydrate, which is the form that is most commonly encountered in commerce and the ...
The color of chemicals is a physical property of chemicals that in most cases comes from the excitation of electrons due to an absorption of energy performed by the chemical. The study of chemical structure by means of energy absorption and release is generally referred to as spectroscopy .
In terms of its being an oxidant, iron(III) chloride oxidizes iron powder to form iron(II) chloride via a comproportionation reaction: [10] 2 FeCl 3 + Fe → 3 FeCl 2. A traditional synthesis of anhydrous ferrous chloride is the reduction of FeCl 3 with chlorobenzene: [25] 2 FeCl 3 + C 6 H 5 Cl → 2 FeCl 2 + C 6 H 4 Cl 2 + HCl
The aquo ligands on iron(II) complexes are labile. It reacts with 1,10-phenanthroline to give the blue iron(II) derivative: When metallic iron (oxidation state 0) is placed in a solution of hydrochloric acid, iron(II) chloride is formed, with release of hydrogen gas, by the reaction Fe 0 + 2 H + → Fe 2+ + H 2
This reaction can be used to remove potassium hexacyanidoferrate(II) from a solution. [citation needed] A famous reaction involves treatment with ferric salts, most commonly Iron(III) chloride, to give Prussian blue. In the reaction with Iron(III) chloride, producing Potassium chloride as a side-product:
The chemical garden relies on most transition metal silicates being insoluble in water and colored. When a metal salt, such as cobalt chloride, is added to a sodium silicate solution, it will start to dissolve. It will then form insoluble cobalt silicate by a double displacement reaction. This cobalt silicate is a semipermeable membrane.
Tris(bipyridine)iron(II) chloride features an octahedral Fe(II) center bound to three 2,2'-Bipyridine ligands. The complex has been isolated as salts with many anions. The complex has been isolated as salts with many anions.
The free radicals generated by this process engage in secondary reactions. For example, the hydroxyl is a powerful, non-selective oxidant. [6] Oxidation of an organic compound by Fenton's reagent is rapid and exothermic and results in the oxidation of contaminants to primarily carbon dioxide and water.