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When a salt of a metal ion, with the generic formula MX n, is dissolved in water, it will dissociate into a cation and anions. [citation needed]+ + (aq) signifies that the ion is aquated, with cations having a chemical formula [M(H 2 O) p] q+ and anions whose state of aquation is generally unknown.
A Piper diagram is a graphical representation of the chemistry of a water sample or samples. The cations and anions are shown by separate ternary plots. The apexes of the cation plot are calcium, magnesium and sodium plus potassium cations. The apexes of the anion plot are sulfate, chloride and carbonate plus hydrogen carbonate anions.
Cations are positively (+) charged ions while anions are negatively (−) charged. This can be remembered with the help of the following mnemonics. Cats have paws ⇔ Cations are pawsitive. [23] Ca+ion: The letter t in cation looks like a + (plus) sign. [24] An anion is a negative ion. (An egative ion ⇒ Anion). [25]
A cation is a positively charged ion with fewer electrons than protons [2] (e.g. K + (potassium ion)) while an anion is a negatively charged ion with more electrons than protons. [ 3 ] (e.g. Cl - (chloride ion) and OH - (hydroxide ion)).
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Metal aqua ions are always accompanied in solution by solvated anions, but much less is known about anion solvation than about cation solvation. [ 6 ] Understanding of the nature of aqua ions is helped by having information on the nature of solvated cations in mixed solvents [ 7 ] and non-aqueous solvents , such as liquid ammonia , methanol ...
In inorganic chemistry, Fajans' rules, formulated by Kazimierz Fajans in 1923, [1] [2] [3] are used to predict whether a chemical bond will be covalent or ionic, and depend on the charge on the cation and the relative sizes of the cation and anion. They can be summarized in the following table:
Non-coordinating anions are anions that interact only weakly with cations, a useful property when studying highly electrophilic cations. [8] In coordination chemistry, the term can also be used to refer to anions which are unlikely to bind directly to the metal centre of a complex. Hexafluorophosphate is a non-coordinating anion in both senses ...