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For gases, departure from 3 R per mole of atoms is generally due to two factors: (1) failure of the higher quantum-energy-spaced vibration modes in gas molecules to be excited at room temperature, and (2) loss of potential energy degree of freedom for small gas molecules, simply because most of their atoms are not bonded maximally in space to ...
CaSiO 3: −1630 Carbon Solid C 0 Carbon Solid C 1.9 Carbon: Gas C 716.67 Carbon dioxide: Gas CO 2: −393.509 Carbon disulfide: Liquid CS 2: 89.41 Carbon disulfide: Gas CS 2: 116.7 Carbon monoxide: Gas CO −110.525 Carbonyl chloride Gas COCl 2: −218.8 Carbon dioxide (un–ionized) Aqueous CO 2 (aq) −419.26 Bicarbonate ion Aqueous HCO 3 –
The molar mass of atoms of an element is given by the relative atomic mass of the element multiplied by the molar mass constant, M u ≈ 1.000 000 × 10 −3 kg/mol ≈ 1 g/mol. For normal samples from Earth with typical isotope composition, the atomic weight can be approximated by the standard atomic weight [ 2 ] or the conventional atomic weight.
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
Chemical engineers once used the kilogram-mole (notation kg-mol), which is defined as the number of entities in 12 kg of 12 C, and often referred to the mole as the gram-mole (notation g-mol), then defined as the number of entities in 12 g of 12 C, when dealing with laboratory data. [6]
These tables list values of molar ionization energies, measured in kJ⋅mol −1.This is the energy per mole necessary to remove electrons from gaseous atoms or atomic ions.
f eq (H 2 SO 4) = 0.5. If the concentration of a sulfuric acid solution is c(H 2 SO 4) = 1 mol/L, then its normality is 2 N. It can also be called a "2 normal" solution. Similarly, for a solution with c(H 3 PO 4) = 1 mol/L, the normality is 3 N because phosphoric acid contains 3 acidic H atoms.
A closely related property of a substance is the heat capacity per mole of atoms, or atom-molar heat capacity, in which the heat capacity of the sample is divided by the number of moles of atoms instead of moles of molecules. So, for example, the atom-molar heat capacity of water is 1/3 of its molar heat capacity, namely 25.3 J⋅K −1 ⋅mol ...