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A solution of nitric acid, water and alcohol, nital, is used for etching metals to reveal the microstructure. ISO 14104 is one of the standards detailing this well known procedure. [45] Nitric acid is used either in combination with hydrochloric acid or alone to clean glass cover slips and glass slides for high-end microscopy applications. [46]
When dissolved, iron(III) nitrate forms yellow solutions. When this solution is heated to near boiling, nitric acid evaporates and a solid precipitate of iron(III) oxide Fe 2 O 3 appears. [7] Another method for producing iron oxides from this nitrate salt involves neutralizing its aqueous solutions. [8]
The iron compounds produced on the largest scale in industry are iron(II) sulfate (FeSO 4 ·7H 2 O) and iron(III) chloride (FeCl 3). The former is one of the most readily available sources of iron(II), but is less stable to aerial oxidation than Mohr's salt ((NH 4) 2 Fe(SO 4) 2 ·6H 2 O). Iron(II) compounds tend to be oxidized to iron(III ...
Iron(III) oxide is insoluble in water but dissolves readily in strong acid, e.g., hydrochloric and sulfuric acids. It also dissolves well in solutions of chelating agents such as EDTA and oxalic acid. Heating iron(III) oxides with other metal oxides or carbonates yields materials known as ferrates (ferrate (III)): [18] ZnO + Fe 2 O 3 → Zn(FeO ...
Nitric acid is a source of nitric oxide complexes, although the details are obscure. Probably relevant is the conventional self-dehydration of nitric acid: 2 HNO 3 → NO 2 + NO 3 − + H 2 O. Nitric acid is used in some preparations of nitroprusside from ferrocyanide: HNO 3 + [Fe(CN) 6] 4-→ [Fe(CN) 5 (NO)] 2-+ OH − + OCN −
The actual identity of the iron species is often vague, but many applications do not demand high purity materials. It is produced on a large scale by treating sulfuric acid, a hot solution of ferrous sulfate, and an oxidizing agent. Typical oxidizing agents include chlorine, nitric acid, and hydrogen peroxide. [5]
Iron(II) nitrate can be produced in multiple ways, such as the reaction of iron metal with cold dilute nitric acid: 3 Fe + 8 HNO 3 + 12 H 2 O → 3 Fe(NO 3) 2 (H 2 O) 6 + 2 NO. If this reaction is conducted below -10 °C, nonahydrate is produced. It readily releases water to give the hexahydrate. [1] The above reaction can also co-produce ...
Crystal structure of iron(II) oxalate dihydrate, showing iron (gray), oxygen (red), carbon (black), and hydrogen (white) atoms. Blood-red positive thiocyanate test for iron(III) Iron(III) complexes are quite similar to those of chromium(III) with the exception of iron(III)'s preference for O-donor instead of N-donor ligands. The latter tend to ...