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Monobromotoluene isomers [1] [2] [3] Common name Structure Systematic name: 1-bromo-2-methylbenzene 1-bromo-3-methylbenzene 1-bromo-4-methylbenzene Molecular formula: C 7 H 7 Br (C 6 H 4 BrCH 3) Molar mass: 171.03 g/mol Appearance colorless liquid colorless liquid white crystalline solid CAS number [95-46-5] [591-17-3]
Together with other isomers, 4-nitrotoluene is prepared by nitration of toluene, [4] commonly using titanium(IV) nitrate. [5] It undergoes the reactions typical for nitrobenzene derivatives, e.g. hydrogenation gives p-toluidine. Oxidation of the methyl substituent of 4-nitrotoluene has been extensively investigated.
Catalytic hydrogenation using: Raney nickel [2] or palladium-on-carbon, [3] [4] [5] platinum(IV) oxide, or Urushibara nickel. [6] Iron in acidic media. [7] [8] [9] Sodium hydrosulfite [10] Sodium sulfide (or hydrogen sulfide and base). Illustrated by the selective reduction of dinitrophenol to the nitroaminophenol. [11] Tin(II) chloride [12 ...
o-Toluidine is absorbed through inhalation and dermal contact as well as from the gastrointestinal tract. [19] [13] [20] [21]The metabolism of o-toluidine involves many competing activating and deactivating pathways, including N-acetylation, N-oxidation, and N-hydroxylation, and ring oxidation.
The reaction mechanism [8] of the Bartoli indole synthesis is illustrated below using o-nitrotoluene (1) and propenyl Grignard (2) to form 3,7-dimethylindole (13). The mechanism of the Bartoli indole synthesis. The mechanism begins by the addition of the Grignard reagent (2) onto the nitroarene (1) to form intermediate 3.
The traditional Béchamp reduction cogenerates gray-black iron oxides. The Laux process is based on the finding that the oxide coproduct is strongly affected by various additives, such as ferrous chloride, aluminium chloride, and even simply sulfuric acid, which are added before heating the iron-nitrobenzene mixture.
4-Nitrobenzaldehyde is an organic compound with the formula O 2 NC 6 H 4 CHO. It is one of three isomers of nitrobenzaldehyde. It contains a nitro group para-substituted to an aldehyde. 4-Nitrobenzaldehyde is obtained by oxidation of 4-nitrotoluene or hydrolysis of 4-nitrobenzalbromide: [3] O 2 NC 6 H 4 CHBr 2 + H 2 O → O 2 NC 6 H 4 CHO + 2 HBr
2-Nitrobenzoic acid is prepared by oxidation of 2-nitrotoluene. 3-Nitrobenzoic acid is a precursor to 3-aminobenzoic acid, which in turn is used to prepare some dyes. It can be prepared by nitration of benzoic acid. It also can be prepared by treating benzaldehyde under nitration conditions, a process that initially converts the aldehyde to the ...