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Chromium nitride is a chemical compound of chromium and nitrogen with the formula CrN. It is very hard, and is extremely resistant to corrosion.It is an interstitial compound, with nitrogen atoms occupying the octahedral holes in the chromium lattice: [2] as such, it is not strictly a chromium(III) compound nor does it contain nitride ions (N 3−).
Chromium compounds are compounds containing the element chromium (Cr). Chromium is a member of group 6 of the transition metals . The +3 and +6 states occur most commonly within chromium compounds, followed by +2; charges of +1, +4 and +5 for chromium are rare, but do nevertheless occasionally exist.
The chemical element nitrogen is one of the most abundant elements in the universe and can form many compounds. It can take several oxidation states; but the most common oxidation states are -3 and +3. Nitrogen can form nitride and nitrate ions. It also forms a part of nitric acid and nitrate salts.
Free nitrogen atoms easily react with most elements to form nitrides, and even when two free nitrogen atoms collide to produce an excited N 2 molecule, they may release so much energy on collision with even such stable molecules as carbon dioxide and water to cause homolytic fission into radicals such as CO and O or OH and H. Atomic nitrogen is ...
Ammonium dichromate – [NH 4] 2 Cr 2 O 7 [42] Ammonium dihydrogen phosphate – [NH 4]H 2 PO 4; Ammonium hexafluoroaluminate – AlF 6 H 12 N 3 [43] Ammonium hexafluorophosphate – F 6 H4 NP [44] Ammonium hexachloroplatinate – [NH 4] 2 [PtCl 6] [45] Ammonium hexafluorosilicate [46] Ammonium hexafluorotitanate [47] Ammonium ...
2 Cr 2 O 7 (s) → Cr 2 O 3 (s) + N 2 (g) + 4 H 2 O (g) (ΔH = −429.1 ± 3 kcal/mol) Like ammonium nitrate, it is thermodynamically unstable. [9] [10] Its decomposition reaction proceeds to completion once initiated, producing voluminous dark green powdered chromium(III) oxide. Not all of the ammonium dichromate decomposes in this reaction.
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Chromium(III) hydroxide (Cr(OH) 3) is amphoteric, dissolving in acidic solutions to form [Cr(H 2 O) 6] 3+, and in basic solutions to form [Cr(OH) 6] 3−. It is dehydrated by heating to form the green chromium(III) oxide (Cr 2 O 3), a stable oxide with a crystal structure identical to that of corundum. [21]