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A cooling curve of naphthalene from liquid to solid. A cooling curve is a line graph that represents the change of phase of matter, typically from a gas to a solid or a liquid to a solid. The independent variable (X-axis) is time and the dependent variable (Y-axis) is temperature. [1] Below is an example of a cooling curve used in castings.
A typical phase diagram.The solid green line applies to most substances; the dashed green line gives the anomalous behavior of water. In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. [1]
The pressure on a pressure-temperature diagram (such as the water phase diagram shown above) is the partial pressure of the substance in question. A phase diagram in physical chemistry , engineering , mineralogy , and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct ...
The main feature of thermodynamic diagrams is the equivalence between the area in the diagram and energy. When air changes pressure and temperature during a process and prescribes a closed curve within the diagram the area enclosed by this curve is proportional to the energy which has been gained or released by the air.
Familiar examples are the melting of ice or the boiling of water (the water does not instantly turn into vapor, but forms a turbulent mixture of liquid water and vapor bubbles). Yoseph Imry and Michael Wortis showed that quenched disorder can broaden a first-order transition. That is, the transformation is completed over a finite range of ...
The figure shows the schematic P-T diagram of a pure substance (as opposed to mixtures, which have additional state variables and richer phase diagrams, discussed below). The commonly known phases solid , liquid and vapor are separated by phase boundaries, i.e. pressure–temperature combinations where two phases can coexist.
The unusual density curve and lower density of ice than of water is essential for much of the life on earth—if water were most dense at the freezing point, then in winter the cooling at the surface would lead to convective mixing. Once 0 °C are reached, the water body would freeze from the bottom up, and all life in it would be killed. [36]
Constitutional supercooling – phase diagram, concentration, and temperature. Constitutional supercooling, which occurs during solidification, is due to compositional solid changes, and results in cooling a liquid below the freezing point ahead of the solid–liquid interface. When solidifying a liquid, the interface is often unstable, and the ...