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An energy profile of an exothermic reaction. In an exothermic reaction, by definition, the enthalpy change has a negative value: ΔH = H products - H reactants < 0. where a larger value (the higher energy of the reactants) is subtracted from a smaller value (the lower energy of the products). For example, when hydrogen burns: 2H 2 (g) + O 2 (g ...
According to the IUPAC, an exothermic reaction is "a reaction for which the overall standard enthalpy change ΔH⚬ is negative". [4] Some examples of exothermic process are fuel combustion, condensation and nuclear fission, [5] which is used in nuclear power plants to release large amounts of energy. [6]
This can be explained with reference to potential energy diagrams: Energy diagrams showing how to interpret Hammond's Postulate. In case (a), which is an exothermic reaction, the energy of the transition state is closer in energy to that of the reactant than that of the intermediate or the product.
In thermochemistry, a thermochemical equation is a balanced chemical equation that represents the energy changes from a system to its surroundings. One such equation involves the enthalpy change, which is denoted with Δ H {\displaystyle \Delta H} In variable form, a thermochemical equation would appear similar to the following:
The energy released by the solvation of the ammonium ions and nitrate ions is less than the energy absorbed in breaking up the ammonium nitrate ionic lattice and the attractions between water molecules. Dissolving potassium hydroxide is exothermic, as more energy is released during solvation than is used in breaking up the solute and solvent.
Electron capture for almost all non-noble gas atoms involves the release of energy [4] and thus is exothermic. The positive values that are listed in tables of E ea are amounts or magnitudes. It is the word "released" within the definition "energy released" that supplies the negative sign to ΔE.
A reaction with a negative Q value is endothermic, i.e. requires a net energy input, since the kinetic energy of the final state is less than the kinetic energy of the initial state. [1] Observe that a chemical reaction is exothermic when it has a negative enthalpy of reaction, in contrast a positive Q value in a nuclear reaction.
Thermal decomposition is a chemical reaction where heat is a reactant. Since heat is a reactant, these reactions are endothermic meaning that the reaction requires thermal energy to break the chemical bonds in the molecule. [1]