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Hexamethylbenzene, also known as mellitene, is a hydrocarbon with the molecular formula C 12 H 18 and the condensed structural formula C 6 (CH 3) 6. It is an aromatic compound and a derivative of benzene , where benzene's six hydrogen atoms have each been replaced by a methyl group .
Number of isomers [3] [4] Number of isomers including stereoisomers [3] [5] Molecular Formula Name of straight chain Synonyms 1 1 1 CH 4: methane: methyl hydride; natural gas 2 1 1 C 2 H 6: ethane: dimethyl; ethyl hydride; methyl methane 3 1 1 C 3 H 8: propane: dimethyl methane; propyl hydride 4 2 2 C 4 H 10: n-butane: butyl hydride ...
For the hydrocarbons with no further unsaturation, there are four isomers. The chemical formula for all the saturated isomers is C 9 H 12 . There are three trimethylbenzenes , three ethylmetylbenzenes, and two propylbenzene isomers. 1980s American gasoline contained about 3-4% C 3 -benzenes.
Examples of simple benzene derivatives are phenol, toluene, and aniline, abbreviated PhOH, PhMe, and PhNH 2, respectively. Linking benzene rings gives biphenyl , C 6 H 5 –C 6 H 5 . Further loss of hydrogen gives "fused" aromatic hydrocarbons, such as naphthalene , anthracene , phenanthrene , and pyrene .
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Alkylbenzene isomers can be differentiated by observing the position of alkyl substituents on the benzene ring using chemical ionization-proton exchange mass spectrometry. Conventional GC-MS yields limited results because the isomers have identical molecular weight and substituents.
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