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Paul Sabatier (1854-1941) winner of the Nobel Prize in Chemistry in 1912 and discoverer of the reaction in 1897. The Sabatier reaction or Sabatier process produces methane and water from a reaction of hydrogen with carbon dioxide at elevated temperatures (optimally 300–400 °C) and pressures (perhaps 3 MPa [1]) in the presence of a nickel catalyst.
Methanation is an important step in the creation of synthetic or substitute natural gas (SNG). [7] Coal or wood undergo gasification which creates a producer gas that must undergo methanation in order to produce a usable gas that just needs to undergo a final purification step.
Carbon dioxide reforming (also known as dry reforming) is a method of producing synthesis gas (mixtures of hydrogen and carbon monoxide) from the reaction of carbon dioxide with hydrocarbons such as methane with the aid of metal catalysts (typically Ni or Ni alloys).
For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.
Peters four-step chemistry is a systematically reduced mechanism for methane combustion, named after Norbert Peters, who derived it in 1985. [1] [2] [3] The mechanism reads as [4]
In chemistry, thermochemical cycles combine solely heat sources (thermo) with chemical reactions to split water into its hydrogen and oxygen components. [1] The term cycle is used because aside of water, hydrogen and oxygen, the chemical compounds used in these processes are continuously recycled.
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A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry.It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by atom or group.