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Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.
Polyhedral representation of spinel MgAl 2 O 4. Spinel (/ s p ɪ ˈ n ɛ l, ˈ s p ɪ n əl / [7]) is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl 2 O 4 in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals. [5]
Maghemite (Fe 2 O 3, γ-Fe 2 O 3) is a member of the family of iron oxides.It has the same formula as hematite, but the same spinel ferrite structure as magnetite (Fe 3 O 4) and is also ferrimagnetic.
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The red spheres are X atoms (usually oxygens), the blue spheres are B atoms (a smaller metal cation, such as Ti 4+), and the green spheres are the A atoms (a larger metal cation, such as Ca 2+). Pictured is the undistorted cubic structure; the symmetry is lowered to orthorhombic, tetragonal or trigonal in many perovskites.
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