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Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.
The red spheres are X atoms (usually oxygens), the blue spheres are B atoms (a smaller metal cation, such as Ti 4+), and the green spheres are the A atoms (a larger metal cation, such as Ca 2+). Pictured is the undistorted cubic structure; the symmetry is lowered to orthorhombic, tetragonal or trigonal in many perovskites.
In condensed matter physics and inorganic chemistry, the cation-anion radius ratio can be used to predict the crystal structure of an ionic compound based on the relative size of its atoms. It is defined as the ratio of the ionic radius of the positively charged cation to the ionic radius of the negatively charged anion in a cation-anion compound.
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Asterism is generated by reflections of light from twin-lamellae or from extremely fine needle-shaped acicular inclusions within the stone's crystal structure. [1] A common cause is oriented sub-microscopic crystals of rutile within the gem mineral. It occurs in rubies, sapphires, garnet, diopside, and spinel when a cabochon is cut from a ...
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