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Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.
Filipstadite is a very rare mineral [4] of the spinel group, with the formula (Mn,Mg)(Sb 5+ 0.5 Fe 3 + 0.5)O 4. [5] It is isometric, [ 3 ] although it was previously thought to be orthorhombic. When compared to a typical spinel, both the octahedral and tetrahedral sites are split due to cation ordering. [ 3 ]
Maghemite (Fe 2 O 3, γ-Fe 2 O 3) is a member of the family of iron oxides.It has the same formula as hematite, but the same spinel ferrite structure as magnetite (Fe 3 O 4) and is also ferrimagnetic.
Hercynite is a spinel of regular symmetry and normal cation distribution, but some disorder occurs in its structure. It consists of ferrous (Fe 2+ ) ions and aluminium ions (Al 3+ ); however some ferric ions (Fe 3+ ) may be located in the structure of hercynite.
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In solution, the cations are thoroughly mixed and held close together by the polymer chains. [11] The water is driven off to produce a foam whose organic components are burned off with a calcining step, producing a fine and pure mixed oxide powder, [ 12 ] which may be pressed into a green body and sintered.
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