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Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. It is used to study and identify chemical substances or functional groups in solid, liquid, or gaseous forms. It can be used to characterize new materials or identify ...
Fourier transform infrared spectroscopy (FTIR) [1] is a technique used to obtain an infrared spectrum of absorption or emission of a solid, liquid, or gas. An FTIR spectrometer simultaneously collects high-resolution spectral data over a wide spectral range.
An infrared spectroscopy correlation table (or table of infrared absorption frequencies) is a list of absorption peaks and frequencies, typically reported in wavenumber, for common types of molecular bonds and functional groups.
Example of a linear molecule. N atoms in a molecule have 3N degrees of freedom which constitute translations, rotations, and vibrations.For non-linear molecules, there are 3 degrees of freedom for translational (motion along the x, y, and z directions) and 3 degrees of freedom for rotational motion (rotations in R x, R y, and R z directions) for each atom.
A Fermi resonance is the shifting of the energies and intensities of absorption bands in an infrared or Raman spectrum. It is a consequence of quantum-mechanical wavefunction mixing. [1] The phenomenon was first explained by the Italian physicist Enrico Fermi. [2]
Image intensifiers are sensitive to this area of the spectrum; examples include night vision devices such as night vision goggles. Near-infrared spectroscopy is another common application. Short-wavelength infrared SWIR, IR-B DIN: 1.4–3 μm 100–214 THz 413–886 meV 2,070–966 K (1,797–693 °C)
It states that no normal modes can be both Infrared and Raman active in a molecule that possesses a center of symmetry. This is a powerful application of group theory to vibrational spectroscopy, and allows one to easily detect the presence of this symmetry element by comparison of the IR and Raman spectra generated by the same molecule. [1]
AFM-IR enables nanoscale infrared spectroscopy, [52] i.e. the ability to obtain infrared absorption spectra from nanoscale regions of a sample. Chemical compositional mapping AFM-IR can also be used to perform chemical imaging or compositional mapping with spatial resolution down to ~10-20 nm, [18] limited only by the radius of the AFM tip. In ...
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