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The first individual alkaloid, morphine, was isolated in 1804 from the opium poppy (Papaver somniferum). [1] Alkaloids are a class of basic, naturally occurring organic compounds that contain at least one nitrogen atom. This group also includes some related compounds with neutral [2] and even weakly acidic properties. [3]
Terpenes are colorless, although impure samples are often yellow. Boiling points scale with molecular size: terpenes, sesquiterpenes, and diterpenes respectively at 110, 160, and 220 °C. Being highly non-polar, they are insoluble in water. Being hydrocarbons, they are highly flammable and have low specific gravity (float on water).
Nonpolar bonds generally occur when the difference in electronegativity between the two atoms is less than 0.5; Polar bonds generally occur when the difference in electronegativity between the two atoms is roughly between 0.5 and 2.0; Ionic bonds generally occur when the difference in electronegativity between the two atoms is greater than 2.0
Protopine is an alkaloid occurring in opium poppy, [2] Corydalis tubers [3] and other plants of the family papaveraceae, like Fumaria officinalis. [4] Protopine is metabolically derived from the benzylisoquinoline alkaloid (S)-Reticuline through a progressive series of five enzymatic transformations: 1) berberine bridge enzyme to -Scoulerine; 2) (S)-cheilanthifoline synthase/CYP719A25 to (S ...
A flavonoid alkaloid also known as a flavoalkaloid is a type of natural product produced by plants that contains both a flavonoid core structure and a nitrogen containing substituent so that the substance is also classified as an alkaloid. [1]
An alkaloid is a naturally occurring nitrogenous organic molecule that has a pharmacological effect on humans and other animals. The name derives from the word alkaline ; originally, the term was used to describe any nitrogen-containing base (an amine in modern terms).
Some alkaloids are more stable as ionic salts than as free base. The salts usually exhibit greater water solubility. Common counterions include chloride, bromide, sulfate, phosphate, nitrate, acetate, oxalate, citrate, and tartrate. Ammonium salts formed from the acid–base reaction with hydrochloric acid are known as hydrochlorides.
The platinichloride B 4 ·H 2 PtCl 6 forms orange-red needles ("B" denotes one mole of the alkaloid base in this and the following formula). Iodine in potassium iodide added to an alcoholic solution of the base in the presence of a little hydrochloric acid gives a characteristic periodide, B 2 ·HI·I 2 , crystallizing in steel-blue needles ...