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In the simplest treatment, such a chain follows the random walk model, where each step taken in a random direction is independent of the directions taken in the previous steps, forming a random coil. The average end-to-end distance for a chain satisfying the random walk model is R 2 = N b 2 {\displaystyle \langle R^{2}\rangle =Nb^{2}} .
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A random-coil conformation can be detected using spectroscopic techniques. The arrangement of the planar amide bonds results in a distinctive signal in circular dichroism. The chemical shift of amino acids in a random-coil conformation is well known in nuclear magnetic resonance (NMR). Deviations from these signatures often indicates the ...
However, when a theta solvent is used, the measured characteristics are independent of the solvent. They depend only on short-range properties of the polymer such as the bond length, bond angles, and sterically favorable rotations. The polymer chain will behave exactly as predicted by the random walk or ideal chain model.
What's In Ina Garten's Meatloaf Recipe? In the tradition of classic meatloaf, Garten’s includes onions, Worcestershire sauce, and ketchup for flavor, and eggs and breadcrumbs to bind it all ...
One quarter was all Ohio State really needed to prove it was better than Oregon. The Buckeyes were already up 7-0 after the first minute and the Ducks had back-to-back three-and-outs to start.
In statistical mechanics, the Zimm–Bragg model is a helix-coil transition model that describes helix-coil transitions of macromolecules, usually polymer chains. Most models provide a reasonable approximation of the fractional helicity of a given polypeptide; the Zimm–Bragg model differs by incorporating the ease of propagation (self-replication) with respect to nucleation.
Tennessee avoided an upset and remained No. 1 in the USA TODAY Sports men's basketball poll, but the rest of the top 10 got shuffled with losses.
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