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In chemistry, ammonolysis (/am·mo·nol·y·sis/) is the process of splitting ammonia into + +. [1] Ammonolysis reactions can be conducted with organic compounds to produce amines (molecules containing a nitrogen atom with a lone pair, :N), [2] or with inorganic compounds to produce nitrides.
The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef Bayer.Bauxite, the most important ore of aluminium, contains only 30–60% aluminium oxide (Al 2 O 3), the rest being a mixture of silica, various iron oxides, and titanium dioxide. [1]
The density of the electrolyte should be less than 2.1 g/ml, so that the molten aluminum separates from the electrolyte and settles properly to the bottom of the electrolysis cell. In addition to AlF 3 , other additives like lithium fluoride may be added to alter different properties (melting point, density, conductivity etc.) of the electrolyte.
The conversion can be effected by many reagents. The nitro group was one of the first functional groups to be reduced. Alkyl and aryl nitro compounds behave differently. Most useful is the reduction of aryl nitro compounds.
Aluminium smelting is the process of extracting aluminium from its oxide, alumina, generally by the Hall-Héroult process.Alumina is extracted from the ore bauxite by means of the Bayer process at an alumina refinery.
The reaction was first used by Antoine Béchamp to reduce nitronaphthalene and nitrobenzene to naphthylamine and aniline, respectively. [3] The Béchamp reduction is broadly applicable to aromatic nitro compounds. [4] [5] Aliphatic nitro compounds are however more difficult to reduce, often remaining as the hydroxylamine. Tertiary aliphatic ...
The hydroxide will also deprotonate the phenol (4) to give a negatively charged phenoxide (5). The negative charge is delocalised into the aromatic ring, making it far more nucleophilic. Nucleophilic attack on the dichlorocarbene gives an intermediate dichloromethyl substituted phenol (7). After basic hydrolysis, the desired product (9) is formed.
Unlike the Gattermann reaction, this reaction is not applicable to phenol and phenol ether substrates. [5] Although the highly unstable formyl chloride was initially postulated as an intermediate, formyl cation (i.e., protonated carbon monoxide), [HCO] + , is now thought to react directly with the arene without the initial formation of formyl ...