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Phosgene is also used to produce monoisocyanates, used as pesticide precursors (e.g. methyl isocyanate (MIC). Aside from the widely used reactions described above, phosgene is also used to produce acyl chlorides from carboxylic acids: R−C(=O)−OH + COCl 2 → R−C(=O)−Cl + HCl + CO 2
A soil ball with indigenous worms in soil amended a few weeks previously with bokashi fermented matter. Bokashi is a process that converts food waste and similar organic matter into a soil amendment which adds nutrients and improves soil texture. It differs from traditional composting methods in several respects. The most important are:
A soil test is a laboratory or in-situ analysis to determine the chemical, physical or biological characteristics of a soil. Possibly the most widely conducted soil tests are those performed to estimate the plant-available concentrations of nutrients in order to provide fertilizer recommendations in agriculture.
In organic chemistry, the Mannich reaction is a three-component organic reaction that involves the amino alkylation of an acidic proton next to a carbonyl (C=O) functional group by formaldehyde (H−CHO) and a primary or secondary amine (−NH 2) or ammonia (NH 3). [1] The final product is a β-amino-carbonyl compound also known as a Mannich base.
Non-carbon nucleophiles such as water, alcohols, amines, and enamines can also react with an α,β-unsaturated carbonyl in a 1,4-addition. [10] Some authors have broadened the definition of the Michael addition to essentially refer to any 1,4-addition reaction of α,β-unsaturated carbonyl compounds.
Paul Sabatier (1854-1941) winner of the Nobel Prize in Chemistry in 1912 and discoverer of the reaction in 1897. The Sabatier reaction or Sabatier process produces methane and water from a reaction of hydrogen with carbon dioxide at elevated temperatures (optimally 300–400 °C) and pressures (perhaps 3 MPa [1]) in the presence of a nickel catalyst.
In even a slight presence of water, carbonic acid dehydrates to carbon dioxide and water, which then catalyzes further decomposition. [6] For this reason, carbon dioxide can be considered the carbonic acid anhydride. The hydration equilibrium constant at 25 °C is [H 2 CO 3]/[CO 2] ≈ 1.7×10 −3 in pure water [12] and ≈ 1.2×10 −3 in ...
In clayey soil, bacteria are capable of reorienting and moving clay particles under low confining stress (at shallow depths). However, inability to make these rearrangements under high confining stresses limits bacterial activity at larger depths. Furthermore, sediment-cell interaction may cause puncture or tensile failure of the cell membrane.