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Partition coefficient. In the physical sciences, a partition coefficient (P) or distribution coefficient (D) is the ratio of concentrations of a compound in a mixture of two immiscible solvents at equilibrium. This ratio is therefore a comparison of the solubilities of the solute in these two liquids. The partition coefficient generally refers ...
In the International System of Units (SI), the coherent unit for molar concentration is mol/m 3. However, most chemical literature traditionally uses mol/dm 3, which is the same as mol/L. This traditional unit is often called a molar and denoted by the letter M, for example: 1 mol/m 3 = 10 −3 mol/dm 3 = 10 −3 mol/L = 10 −3 M = 1 mM = 1 ...
For example, sulfuric acid (H 2 SO 4) is a diprotic acid. Since only 0.5 mol of H 2 SO 4 are needed to neutralize 1 mol of OH −, the equivalence factor is: feq (H 2 SO 4) = 0.5. If the concentration of a sulfuric acid solution is c (H 2 SO 4) = 1 mol/L, then its normality is 2 N. It can also be called a "2 normal" solution.
hide. In chemistry, the rate equation (also known as the rate law or empirical differential rate equation) is an empirical differential mathematical expression for the reaction rate of a given reaction in terms of concentrations of chemical species and constant parameters (normally rate coefficients and partial orders of reaction) only. [ 1 ]
In this method the chemical equation is used to calculate the amount of one product which can be formed from each reactant in the amount present. The limiting reactant is the one which can form the smallest amount of the product considered. This method can be extended to any number of reactants more easily than the first method.
Euler's constant (sometimes called the Euler–Mascheroni constant) is a mathematical constant, usually denoted by the lowercase Greek letter gamma (γ), defined as the limiting difference between the harmonic series and the natural logarithm, denoted here by log: Here, ⌊·⌋ represents the floor function.
N i is the number of particles (or number of moles) composing the i-th chemical component. This is one form of the Gibbs fundamental equation . [ 10 ] In the infinitesimal expression, the term involving the chemical potential accounts for changes in Gibbs free energy resulting from an influx or outflux of particles.
Dissociation constant. In chemistry, biochemistry, and pharmacology, a dissociation constant (KD) is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, as when a complex falls apart into its component molecules, or when a salt splits up into its ...