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[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
α-Calcium nitride adopts an anti-bixbyite structure, similar to Mn 2 O 3, except that the positions of the ions are reversed: calcium (Ca 2+) take the oxide (O 2−) positions and nitride ions (N 3−) the manganese (Mn 3+). In this structure, Ca 2+ occupies tetrahedral sites, and the nitride centres occupy two different types of octahedral ...
Sodium nitride and potassium nitride has been generated, but remains a laboratory curiosity. The nitrides of the alkaline earth metals that have the formula M 3 N 2 are however numerous. Examples include beryllium nitride (Be 3 N 2), magnesium nitride (Mg 3 N 2), calcium nitride (Ca 3 N 2), and strontium nitride (Sr 3 N 2). The nitrides of ...
ZrN grown by physical vapor deposition (PVD) is a light gold color similar to elemental gold. ZrN has a room-temperature electrical resistivity of 12.0 μΩ·cm, a temperature coefficient of resistivity of 5.6·10 −8 Ω·cm/K, a superconducting transition temperature of 10.4 K, and a relaxed lattice parameter of 0.4575 nm.
The trihalides adopt a planar trigonal structure. These compounds are Lewis acids in that they readily form adducts with electron-pair donors, which are called Lewis bases. For example, fluoride (F −) and boron trifluoride (BF 3) combined to give the tetrafluoroborate anion, BF 4 −. Boron trifluoride is used in the petrochemical industry as ...
Lithium nitride is prepared by direct reaction of elemental lithium with nitrogen gas: [2] 6 Li + N 2 → 2 Li 3 N. Instead of burning lithium metal in an atmosphere of nitrogen, a solution of lithium in liquid sodium metal can be treated with N 2. Lithium nitride must be protected from moisture as it reacts violently with water to produce ammonia:
Magnesium cyanide is a chemical compound with the formula Mg(CN) 2. It is a toxic white solid. Unlike calcium isocyanide, the cyanide ligands prefer to coordinate at carbon, with a 0.3‑kcal/mol isomerization barrier. [1] When this salt is heated to 500 °C, it decomposes to magnesium nitride. [2]
As both the magnesium metal and the product are sensitive to water, the reaction must take place in anhydrous conditions. [3] C 3 H 6 −Br + Mg → C 3 H 6 −Mg−Br. While the product is often portrayed as simply C 3 H 6 MgBr, in reality it will quickly form a tetrahedral coordination complex with the Lewis basic solvent, centred on the ...