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In thermodynamics, dissipation is the result of an irreversible process that affects a thermodynamic system.In a dissipative process, energy (internal, bulk flow kinetic, or system potential) transforms from an initial form to a final form, where the capacity of the final form to do thermodynamic work is less than that of the initial form.
Non-photochemical quenching (NPQ) is a mechanism employed by plants and algae to protect themselves from the adverse effects of high light intensity.It involves the quenching of singlet excited state chlorophylls (Chl) via enhanced internal conversion to the ground state (non-radiative decay), thus harmlessly dissipating excess excitation energy as heat through molecular vibrations.
The concept of 'dissipation of energy' was used in Lord Kelvin's 1852 article "On a Universal Tendency in Nature to the Dissipation of Mechanical Energy." [15] He distinguished between two types or "stores" of mechanical energy: "statical" and "dynamical." He discussed how these two types of energy can change from one form to the other during a ...
This process involves the dissipation of energy from the molecule to its surroundings, and thus it cannot occur for isolated molecules. A second type of nonradiative transition is internal conversion (IC), which occurs when a vibrational state of an electronically excited state can couple to a vibrational state of a lower electronic state. The ...
The typical approach to describe dissipation is to split the total system in two parts: the quantum system where dissipation occurs, and a so-called environment or bath into which the energy of the former will flow. The way both systems are coupled depends on the details of the microscopic model, and hence, the description of the bath.
In physics, the dissipation factor (DF) is a measure of loss-rate of energy of a mode of oscillation (mechanical, electrical, or electromechanical) in a dissipative system. It is the reciprocal of quality factor , which represents the "quality" or durability of oscillation.
In thermodynamics, the Gibbs free energy (or Gibbs energy as the recommended name; symbol ) is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure–volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure.
The physical interpretation is that () is the energy stored in the system, whereas ((), ()) is the energy that is supplied to the system. This notion has a strong connection with Lyapunov stability , where the storage functions may play, under certain conditions of controllability and observability of the dynamical system, the role of Lyapunov ...
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