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Phenylpropanoic acid or hydrocinnamic acid is a carboxylic acid with the formula C 9 H 10 O 2 belonging to the class of phenylpropanoids. It is a white, crystalline solid with a sweet, floral scent at room temperature. Phenylpropanoic acid has a wide variety of uses including cosmetics, food additives, and pharmaceuticals. [5]
Phenylpropanoic acid Index of chemical compounds with the same molecular formula This set index page lists chemical structure articles associated with the same molecular formula .
Hydroxylation of cinnamic acid in the 4-position by trans-cinnamate 4-monooxygenase leads to p-coumaric acid, which can be further modified into hydroxylated derivatives such as umbelliferone. Another use of p -coumaric acid via its thioester with coenzyme A , i.e. 4-coumaroyl-CoA , is the production of chalcones .
In chemistry, the hydrogenation of carbon–nitrogen double bonds is the addition of the elements of dihydrogen (H 2) across a carbon–nitrogen double bond, forming amines or amine derivatives. [1] Although a variety of general methods have been developed for the enantioselective hydrogenation of ketones, [ 2 ] methods for the hydrogenation of ...
Chromic acid oxidizes it to benzoic acid; zinc and acetic acid reduce it to cinnamic acid, C 6 H 5 CH=CHCO 2 H, whilst sodium amalgam reduces it to hydrocinnamic acid, C 6 H 5 CH 2 CH 2 CO 2 H. Ortho-nitrophenylpropiolic acid, NO 2 C 6 H 4 CCCO 2 H, prepared by the action of alcoholic potash on ortho-nitrocinnamic acid dibromide, crystallizes ...
Phenylacetic, 3-phenylpropanoic and 3-phenylpropenoic acids are found in propolis, mammalian exocrine secretions or plant fragrances. During a systematic study of the lipids from seeds of the plant Araceae, [1] the presence of 13-phenyltridecanoic acid as a major component (5-16% of total fatty acids)was discovered. Other similar compounds but ...
Two broad strategies exist for carbonyl reduction. One method, which is favored in industry, uses hydrogen as the reductant. This approach is called hydrogenation and requires metal catalysts. The other broad approach employs stoichiometric reagents that deliver H − and H + separately. This article focuses on the use of these reagents.
The Guerbet reaction, reported in 1899, [5] is an early example of a hydrogen auto-transfer process. The Guerbet reaction converts primary alcohols to β-alkylated dimers via alcohol dehydrogenation followed by aldol condensation and reduction of the resulting enones.