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4 bind to strongly electrophilic metal centers of the type use in some catalytic reactions. [ 2 ] [ 3 ] Tetrafluoroborate and hexafluorophosphate anions are coordinating toward highly electrophilic metal ions, such as cations containing Zr(IV) centers, which can abstract fluoride from these anions.
In most cases these decays change the value of the strangeness by one unit. This doesn't necessarily hold in second-order weak reactions, however, where there are mixes of K 0 and K 0 mesons. All in all, the amount of strangeness can change in a weak interaction reaction by +1, 0 or −1 (depending on the reaction).
The following list includes the metallic elements of the first six periods. It is mostly based on tables provided by NIST. [9] [10] However, not all sources give the same values: there are some differences between the precise values given by NIST and the CRC Handbook of Chemistry and Physics. In the first six periods this does not make a ...
The reaction usually occurs in the complete absence of a base or the presence of only a weak base (acidic conditions and high temperature). E1 reactions are in competition with S N 1 reactions because they share a common carbocationic intermediate. A secondary deuterium isotope effect of slightly larger than 1 (commonly 1 - 1.5) is observed.
Redox reactions (see list of oxidants and reductants) Reduction; Reductive elimination; Reppe synthesis; Riley oxidation; Salt metathesis; Sarett oxidation; Sharpless epoxidation; Shell higher olefin process; Silylation; Simmons–Smith reaction; Sonogashira coupling; Staudinger reaction; Stille reaction; Sulfidation; Suzuki reaction ...
Strict weak orders are very closely related to total preorders or (non-strict) weak orders, and the same mathematical concepts that can be modeled with strict weak orderings can be modeled equally well with total preorders. A total preorder or weak order is a preorder in which any two elements are comparable. [7]
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Salt metathesis reaction; Salt-free reduction; Scavenger resin; Screaming jelly babies; SEA Native Peptide Ligation; Self-assembling peptide; Semiclassical transition state theory; Shiina esterification; Side reaction; Single displacement reaction; Small molecule sensors; Solid-state reaction route; Spin-forbidden reactions; Stripping reaction ...