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Ferric acetate is the iron compound with the formula Fe 3 O(O 2 CCH 3) 6 (H 2 O) 3]O 2 CCH 3. This red brown solid is the acetate salt of the coordination complex [Fe 3 O(OAc) 6 (H 2 O) 3] + (OAc − is CH 3 CO 2 −). Commonly, the salt is known as "basic iron acetate". [2] The formation of the red-brown complex was once used as a test for ...
Iron(II) acetate describes compounds with formula Fe(CH 3 CO 2) 2 ·(H 2 O) x where x can be 0 (anhydrous) or 4 (tetrahydrate). The anhydrous compound is a white solid, although impure samples can be slightly colored. [1] The tetrahydrate is light green solid that is highly soluble in water.
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A molecular ferric complex is the anion ferrioxalate, [Fe(C 2 O 4) 3] 3−, with three bidentate oxalate ions surrounding the Fe core. Relative to lower oxidation states, ferric is less common in organoiron chemistry , but the ferrocenium cation [Fe(C 2 H 5 ) 2 ] + is well known.
The compound can be prepared by treating nickel or nickel(II) carbonate with acetic acid: . NiCO 3 + 2 CH 3 CO 2 H + 3 H 2 O → Ni(CH 3 CO 2) 2 ·4 H 2 O + CO 2. The mint-green tetrahydrate has been shown by X-ray crystallography to adopt an octahedral structure, the central nickel centre being coordinated by four water molecules and two acetate ligands. [5]
Ferric oxalate, also known as iron(III) oxalate, refers to inorganic compounds with the formula Fe 2 (C 2 O 4) 3 (H 2 O) x but could also refer to salts of [Fe(C 2 O 4) 3] 3-. Fe 2 (C 2 O 4) 3 (H 2 O) x are coordination polymers with varying degrees of hydration. The coordination complex with the formula [Fe(C 2 O 4) 3] 3-forms a variety of ...
Fe 2 O 3 + 3 CO → 2 Fe + 3 CO 2. Another redox reaction is the extremely exothermic thermite reaction with aluminium. [17] 2 Al + Fe 2 O 3 → 2 Fe + Al 2 O 3. This process is used to weld thick metals such as rails of train tracks by using a ceramic container to funnel the molten iron in between two sections of rail.
Other sources of Fe(CO) 3 are Fe 2 (CO) 9 and Fe(CO) 3 (cyclooctene) 2. The latter is highly reactive and thermally sensitive. The latter is highly reactive and thermally sensitive. Imine derivatives of cinnamaldehyde , e.g. C 6 H 5 CH=CHC(H)=NC 6 H 5 , also form reactive Fe(CO) 3 adducts , which have been shown to be superior in some ways to ...