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Reactions of barium hydroxide with ammonium salts are strongly endothermic. The reaction of barium hydroxide octahydrate with ammonium chloride [18] [19] or [20] ammonium thiocyanate [20] [21] is often used as a classroom chemistry demonstration, producing temperatures cold enough to freeze water and enough water to dissolve the resulting mixture.
Barium hydride is a chemical compound with the chemical formula BaH 2. [1] ... Barium hydride reacts with oxygen and water.
Barium chloride is an inorganic compound with the formula Ba Cl 2. It is one of the most common water-soluble salts of barium . Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame.
Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
Barium nitrate is the inorganic compound with the chemical formula Ba(NO 3) 2. It, like most barium salts, is colorless, toxic, and water-soluble. It burns with a green flame and is an oxidizer; the compound is commonly used in pyrotechnics. [4]
[9]: 2–3 Reactions with water and alcohols are also exothermic and release hydrogen gas: [9]: 3 Ba + 2 ROH → Ba(OR) 2 + H 2 ↑ (R is an alkyl group or a hydrogen atom) Barium reacts with ammonia to form the electride [Ba(NH 3) 6](e-) 2, which near room temperature gives the amide Ba(NH 2) 2. [11] The metal is readily attacked by acids.
The reaction is performed in solution and the barium acetate crystalizes out at temperatures above 41 °C. Between 25 and 40 °C, the monohydrate version crystalizes. Alternatively, barium sulfide can be used: [2] BaS + 2 CH 3 COOH → (CH 3 COO) 2 Ba + H 2 S. Again, the solvent is evaporated off and the barium acetate crystallized.
Barium carbonate is the inorganic compound with the formula BaCO 3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of the most important barium compounds. [5]