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Pyridinium perbromide (also called pyridinium bromide perbromide, pyridine hydrobromide perbromide, or pyridinium tribromide) is an organic chemical composed of a pyridinium cation and a tribromide anion. It can also be considered as a complex containing pyridinium bromide—the salt of pyridine and hydrogen bromide—with an added bromine (Br ...
Pyridinium refers to the cation [C 5 H 5 NH] +. It is the conjugate acid of pyridine . Many related cations are known involving substituted pyridines, e.g. picolines, lutidines, collidines.
meso-Stilbene dibromide is an organic compound with a formula of (C 6 H 5 CH(Br)) 2. [3] It is one of three isomeric stilbene dibromides, the others being the pair of enantiomers. All are white solids. [4]
Tribromide is the anion with the chemical formula Br 3 −, or salts containing it: . Tetrabutylammonium tribromide; Tetrabromophosphonium tribromide; Pyridinium perbromide; Sodium and potassium tribromides can be prepared by reacting NaBr or KBr with aqueous bromine.
With a pK a of 5.25 for its conjugate acid, pyridine is about 15x less basic than imidazole. Pyridine is a weak pi-acceptor ligand. Trends in the M-N distances for complexes of the type [MCl 2 (py) 4] 2+ reveal an anticorrelation with d-electron count. [2]
Bromoantimonates can have antimony in one of two oxidation states, either +3 or +5.These are designated by bromoantimonate(III) or bromoantimonate(V). Although antimony tribromide is known, SbBr 5 on its own does not exist, despite the existence of SbBr − 6. [1]
In organic synthesis, PPTS is used as a weakly acidic catalyst, providing an organic soluble source of pyridinium (C 5 H 5 NH +) ions.For example, PPTS is used to deprotect silyl ethers or tetrahydropyranyl ethers when a substrate is unstable to stronger acid catalysts.
The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet ( MSDS ) for this chemical from a reliable source such as eChemPortal , and follow its directions.
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