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The KP equation was first written in 1970 by Soviet physicists Boris B. Kadomtsev (1928–1998) and Vladimir I. Petviashvili (1936–1993); it came as a natural generalization of the KdV equation (derived by Korteweg and De Vries in 1895). Whereas in the KdV equation waves are strictly one-dimensional, in the KP equation this restriction is ...
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
Quantities, Units and Symbols in Physical Chemistry, also known as the Green Book, is a compilation of terms and symbols widely used in the field of physical chemistry. It also includes a table of physical constants , tables listing the properties of elementary particles , chemical elements , and nuclides , and information about conversion ...
The free energy change, dG r, can be expressed as a weighted sum of change in amount times the chemical potential, the partial molar free energy of the species. The chemical potential, μ i, of the ith species in a chemical reaction is the partial derivative of the free energy with respect to the number of moles of that species, N i
The standard state of a material (pure substance, mixture or solution) is a reference point used to calculate its properties under different conditions.A degree sign (°) or a superscript Plimsoll symbol (⦵) is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (ΔH°), change in entropy (ΔS°), or change in Gibbs free energy (ΔG°).
In chemistry, the molar mass (M) (sometimes called molecular weight or formula weight, but see related quantities for usage) of a chemical compound is defined as the ratio between the mass and the amount of substance (measured in moles) of any sample of the compound. [1] The molar mass is a bulk, not molecular, property of a substance.
In thermochemistry, a thermochemical equation is a balanced chemical equation that represents the energy changes from a system to its surroundings. One such equation involves the enthalpy change, which is denoted with Δ H {\displaystyle \Delta H} In variable form, a thermochemical equation would appear similar to the following:
Considering finite changes instead of infinitesimal changes, one can write the equation for the extent of a reaction as = The extent of a reaction is generally defined as zero at the beginning of the reaction. Thus the change of is the extent itself. Assuming that the system has come to equilibrium,