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The thiocarbonate moiety can be functionalized at the R-group for end group analysis. The end group is a result of the propagation of chain-transfer agents during the free-radical polymerization process. The end groups can subsequently be modified by the reaction of the thiocarbonylthio compounds with nucleophiles and ionic reducing agents. [11]
In organic chemistry, a vinyl group (abbr. Vi; [1] IUPAC name: ethenyl group [2]) is a functional group with the formula −CH=CH 2. It is the ethylene (IUPAC name: ethene) molecule (H 2 C=CH 2) with one fewer hydrogen atom. The name is also used for any compound containing that group, namely R−CH=CH 2 where R is any other group of atoms.
The Green Book is a direct successor of the Manual of Symbols and Terminology for Physicochemical Quantities and Units, originally prepared for publication on behalf of IUPAC's Physical Chemistry Division by M. L. McGlashen in 1969. A full history of the Green Book's various editions is provided in the historical introduction to the third edition.
IUPAC states that, "As one of its major activities, IUPAC develops Recommendations to establish unambiguous, uniform, and consistent nomenclature and terminology for specific scientific fields, usually presented as: glossaries of terms for specific chemical disciplines; definitions of terms relating to a group of properties; nomenclature of chemical compounds and their classes; terminology ...
Example: 2,2,3-trimethyl- . If there are both double bonds and triple bonds, "en" (double bond) is written before "yne" (triple bond). When the main functional group is a terminal functional group (a group which can exist only at the end of a chain, like formyl and carboxyl groups), there is no need to number it.
This glossary of chemistry terms is a list of terms and definitions relevant to chemistry, including chemical laws, diagrams and formulae, laboratory tools, glassware, and equipment. Chemistry is a physical science concerned with the composition, structure, and properties of matter , as well as the changes it undergoes during chemical reactions ...
Nomenclature of Organic Chemistry, commonly referred to by chemists as the Blue Book, is a collection of recommendations on organic chemical nomenclature published at irregular intervals by the International Union of Pure and Applied Chemistry (IUPAC).
The Hill system (or Hill notation) is a system of writing empirical chemical formulae, molecular chemical formulae and components of a condensed formula such that the number of carbon atoms in a molecule is indicated first, the number of hydrogen atoms next, and then the number of all other chemical elements subsequently, in alphabetical order ...