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The reactivity of a functional group can be modified by other functional groups nearby. Functional group interconversion can be used in retrosynthetic analysis to plan organic synthesis. A functional group is a group of atoms in a molecule with distinctive chemical properties, regardless of the other atoms in the molecule. The atoms in a ...
The structure of the acetoxy group blue. In organic chemistry, the acetoxy group (abbr. AcO or OAc; IUPAC name: acetyloxy [1]), is a functional group with the formula −OCOCH 3 and the structure −O−C(=O)−CH 3. As the -oxy suffix implies, it differs from the acetyl group (−C(=O)−CH 3) by the presence of an additional oxygen atom.
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The mechanism was proposed in 1921 by the eminent German organic chemist Heinrich Wieland and his student Georg Scheuing (1895–1949). [10] [11] Bisulphite was believed to react with the available aromatic amine functional groups to form N-sulfinic acid groups, Ar-NH-SO 2 H, followed by reaction with aldehyde to form sulfonamides, Ar-NH-SO 2 CH
SAMs on nanoparticles, including colloids and nanocrystals, "stabilize the reactive surface of the particle and present organic functional groups at the particle-solvent interface". [1] These organic functional groups are useful for applications, such as immunoassays or sensors , that are dependent on chemical composition of the surface.
The Chong groups have demonstrated using hydrostannation, using Bu 3 SnH with palladium catalyst with high E stereoselectivity. [13] They observed using sterically bulky ligands gave higher regioselectivity for β-vinyl iodide. The advantage of this technique is this technique can tolerate a wide range of functional groups.
This reaction proceeds through deprotonation by organolithium reagents at the positions α to the direct metalation group (DMG) on the aromatic ring. The DMG is often a functional group containing a heteroatom that is Lewis basic, and can coordinate to the Lewis-acidic lithium cation. This generates a complex-induced proximity effect, which ...
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