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Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula H 2 SO 4. It is a colorless, odorless, and viscous liquid that is miscible with water. [7] Structure ...
Given the very small fractionation of 18 O that usually accompanies MSO, the relatively higher depletions in 18 O of the sulfate produced by MSO coupled to DNR (-1.8 to -8.5 ‰) suggest a kinetic isotope effect in the incorporation of oxygen from water to sulfate and the role of nitrate as a potential alternative source of light oxygen. [63]
Concentrated sulfuric acid is a strong dehydrating agent that can strip available water molecules and water components from sugar and organic tissue. [141] The burning of coal and/or petroleum by industry and power plants generates sulfur dioxide (SO 2) that reacts with atmospheric water and oxygen to produce sulfurous acid (H 2 SO 3). [142]
In order to have sufficient redox potential, microorganisms that use sulfur as an electron donor often use oxygen or nitrate as terminal electron acceptors. [4] Members of the chemotrophic Acidithiobacillus genus are able to oxidize a vast range of reduced sulfur compounds, but are restricted to acidic environments. [5]
Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
Treatment of sulfur with hydrogen gives hydrogen sulfide.When dissolved in water, hydrogen sulfide is mildly acidic: [5] H 2 S ⇌ HS − + H +. Hydrogen sulfide gas and the hydrosulfide anion are extremely toxic to mammals, due to their inhibition of the oxygen-carrying capacity of hemoglobin and certain cytochromes in a manner analogous to cyanide and azide.
Sulfuric acid contains two hydroxy groups.. Water, alcohols, carboxylic acids, and many other hydroxy-containing compounds can be readily deprotonated due to a large difference between the electronegativity of oxygen (3.5) and that of hydrogen (2.1).
The most important chemical sodium sulfate production is during hydrochloric acid production, either from sodium chloride (salt) and sulfuric acid, in the Mannheim process, or from sulfur dioxide in the Hargreaves process. [21] The resulting sodium sulfate from these processes is known as salt cake. Mannheim: 2 NaCl + H 2 SO 4 → 2 HCl + Na 2 SO 4