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An electron donating group (EDG) or electron releasing group (ERG, Z in structural formulas) is an atom or functional group that donates some of its electron density into a conjugated π system via resonance (mesomerism) or inductive effects (or induction)—called +M or +I effects, respectively—thus making the π system more nucleophilic.
An electron-withdrawing group (EWG) is a group or atom that has the ability to draw electron density toward itself and away from other adjacent atoms. [1] This electron density transfer is often achieved by resonance or inductive effects.
For meta-directing groups (electron withdrawing group or EWG), σ meta and σ para are more positive than σ’. (The superscript, c, in table denotes data from Hammett, 1940. [11] [page needed]) For ortho-para directing groups (electron donating group or EDG), σ’ more positive than σ meta and σ para.
A Connecticut man who allegedly killed a woman and her infant son in November targeted the woman because she owed him $400 for renting a vehicle of his, arrest reports said on Monday.
Nikki Glaser made history at the 2025 Golden Globes and took full advantage of her moment by poking fun at multiple celebrities in her monologue.
Cranberry Mimosa. Iowa, Kentucky, North Carolina, South Carolina, Virginia, Louisiana, Hawaii . Seven states seem to prefer a Christmas brunch drink for the holidays.
In organic chemistry, the term stereoelectronic effect is also used to emphasize the relation between the electronic structure and the geometry (stereochemistry) of a molecule. The term polar effect is sometimes used to refer to electronic effects, but also may have the more narrow definition of effects resulting from non-conjugated substituents.
The different definitions came from the practice of quoting gravimetric results as mass fractions of the analyte, often expressed as a percentage. A related term was the equivalence factor, one gram divided by equivalent weight, which was the numerical factor by which the mass of precipitate had to be multiplied to obtain the mass of analyte.