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The van Deemter equation is a hyperbolic function that predicts that there is an optimum velocity at which there will be the minimum variance per unit column length and, thence, a maximum efficiency. The van Deemter equation was the result of the first application of rate theory to the chromatography elution process.
A review by Berthod [19] studied the combined theories presented above and applied the Knox equation to independently determine the cause of the reduced efficiency. The Knox equation is commonly used in HPLC to describe the different contributions to overall band broadening of a solute. The Knox equation is expressed as: h = An^(1/3)+ B/n + Cn ...
In fluid dynamics, the Kirchhoff equations, named after Gustav Kirchhoff, describe the motion of a rigid body in an ideal fluid. = + + +, = + +, = (~ +) = ^, = ^ where and are the angular and linear velocity vectors at the point , respectively; ~ is the moment of inertia tensor, is the body's mass; ^ is a unit normal vector to the surface of the body at the point ; is a pressure at this point ...
HPLC has many applications in both laboratory and clinical science. It is a common technique used in pharmaceutical development, as it is a dependable way to obtain and ensure product purity. [59] While HPLC can produce extremely high quality (pure) products, it is not always the primary method used in the production of bulk drug materials. [60]
The equation is named after Edward Wight Washburn; [1] also known as Lucas–Washburn equation, considering that Richard Lucas [2] wrote a similar paper three years earlier, or the Bell-Cameron-Lucas-Washburn equation, considering J.M. Bell and F.K. Cameron's discovery of the form of the equation in 1906.
The Cambridge Handbook of Physics Formulas. Cambridge University Press. ISBN 978-0-521-57507-2. A. Halpern (1988). 3000 Solved Problems in Physics, Schaum Series. Mc Graw Hill. ISBN 978-0-07-025734-4. R.G. Lerner, G.L. Trigg (2005). Encyclopaedia of Physics (2nd ed.). VHC Publishers, Hans Warlimont, Springer. pp. 12– 13.
Equation [3] involves the average velocity v + v 0 / 2 . Intuitively, the velocity increases linearly, so the average velocity multiplied by time is the distance traveled while increasing the velocity from v 0 to v, as can be illustrated graphically by plotting velocity against time as a straight line graph. Algebraically, it follows ...
A twist is a screw used to represent the velocity of a rigid body as an angular velocity around an axis and a linear velocity along this axis. All points in the body have the same component of the velocity along the axis, however the greater the distance from the axis the greater the velocity in the plane perpendicular to this axis.