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In an iodine clock reaction, colour changes after a time delay.. A chemical clock (or clock reaction) is a complex mixture of reacting chemical compounds in which the onset of an observable property (discoloration or coloration) occurs after a predictable induction time due to the presence of clock species at a detectable amount. [1]
Where the rate of heat conduction is high between system domains, hot spots would have no long-term existence as the components rapidly reach thermal equilibrium. In a system where the heat transfer is slow, it would be possible to have the presence of a steady state hot spot that may enhance the rate of the chemical reaction within that hot zone.
The stopped-flow method relies on the presence of spectroscopic properties to monitor reactions in real time. When such properties are unavailable, quenched-flow provides an alternative by using conventional chemical analysis. [8] Instead of a mechanical stopping system, the reaction is halted by quenching, where the products are immediately ...
Chemical reactions: The rates of certain types of chemical reactions depend on the concentration of one or another reactant. Reactions whose rate depends only on the concentration of one reactant (known as first-order reactions) consequently follow exponential decay. For instance, many enzyme-catalyzed reactions behave this way.
On the other hand, when is very low, heat conduction time is much faster than the chemical reaction time, such that all the heat produced by the chemical reaction is immediately conducted to the wall, thus there is no explosion, it goes to an almost steady state, Amable Liñán coined this mode as slowly reacting mode.
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the ...
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics , which deals with the direction in which a reaction occurs but in itself tells nothing about its rate.