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Mass transfer coefficients can be estimated from many different theoretical equations, correlations, and analogies that are functions of material properties, intensive properties and flow regime (laminar or turbulent flow). Selection of the most applicable model is dependent on the materials and the system, or environment, being studied.
Here, is the overall mass transfer coefficient, which could be determined by empirical correlations, is the surface area for mass transfer (particularly relevant in membrane-based separations), and ˙ is the mass flowrate of bulk fluid (e.g., mass flowrate of air in an application where water vapor is being separated from the air mixture). At ...
A major disadvantage of the Maxwell–Stefan theory is that the diffusion coefficients, with the exception of the diffusion of dilute gases, do not correspond to the Fick's diffusion coefficients and are therefore not tabulated. Only the diffusion coefficients for the binary and ternary case can be determined with reasonable effort.
The analogy is useful for both using heat and mass transport to predict one another, or for understanding systems which experience simultaneous heat and mass transfer. For example, predicting heat transfer coefficients around turbine blades is challenging and is often done through measuring evaporating of a volatile compound and using the ...
Dimensionless numbers (or characteristic numbers) have an important role in analyzing the behavior of fluids and their flow as well as in other transport phenomena. [1] They include the Reynolds and the Mach numbers, which describe as ratios the relative magnitude of fluid and physical system characteristics, such as density, viscosity, speed of sound, and flow speed.
This equation permits the prediction of an unknown transfer coefficient when one of the other coefficients is known. The analogy is valid for fully developed turbulent flow in conduits with Re > 10000, 0.7 < Pr < 160, and tubes where L/d > 60 (the same constraints as the Sieder–Tate correlation). The wider range of data can be correlated by ...
The problem of diffusion in the atmosphere is often reduced to that of solving the original gradient based diffusion equation under the appropriate boundary conditions. This theory is often called the K theory, where the name comes from the diffusivity coefficient K introduced in the gradient based theory.
D is the mass diffusivity (m 2 /s). μ is the dynamic viscosity of the fluid (Pa·s = N·s/m 2 = kg/m·s) ρ is the density of the fluid (kg/m 3) Pe is the Peclet Number; Re is the Reynolds Number. The heat transfer analog of the Schmidt number is the Prandtl number (Pr). The ratio of thermal diffusivity to mass diffusivity is the Lewis number ...