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A steel bottle containing MgCp 2 (magnesium bis-cyclopentadienyl), which, like several other organometallic compounds, is pyrophoric in air.. Organometallic compounds are distinguished by the prefix "organo-" (e.g., organopalladium compounds), and include all compounds which contain a bond between a metal atom and a carbon atom of an organyl group. [2]
Main group organometallic chemistry concerns the preparation and properties of main-group elements directly bonded to carbon. The inventory is large. The inventory is large. The compounds exhibit a wide range of properties, including ones that are water-stable and others that are pyrophoric . [ 1 ]
Organozirconium chemistry is the science of exploring the properties, structure, and reactivity of organozirconium compounds, which are organometallic compounds containing chemical bonds between carbon and zirconium. [2] Organozirconium compounds have been widely studied, in part because they are useful catalysts in Ziegler-Natta polymerization.
The isolobal analogy can also be used with isoelectronic fragments having the same coordination number, which allows charged species to be considered. For example, Re(CO) 5 is isolobal with CH 3 and therefore, [Ru(CO) 5] + and [Mo(CO) 5] − are also isolobal with CH 3. Any 17-electron metal complex would be isolobal in this example.
Many examples of homogeneous catalysis involving organometallic complexes involve shuttling of complexes between 16- and 18-electron configurations. 16-electron complexes often form adducts with Lewis bases and, if low-valent, undergo oxidative addition. CH 3 I + cis-[Rh(CO) 2 I 2] − → [(CH 3)Rh(CO) 2 I 3] −
The most famous example is Vaska's complex (IrCl(CO)(PPh 3) 2), [PtCl 4] 2−, and Zeise's salt [PtCl 3 (η 2-C 2 H 4)] −. In such complexes, the d z 2 orbital is doubly occupied and nonbonding. Many catalytic cycles operate via complexes that alternate between 18-electron and square-planar 16-electron configurations.
Organonickel chemistry is a branch of organometallic chemistry that deals with organic compounds featuring nickel-carbon bonds. [1] [2] They are used as a catalyst, as a building block in organic chemistry and in chemical vapor deposition. Organonickel compounds are also short-lived intermediates in organic reactions.
Group 2 organometallic chemistry refers to the organic derivativess of any group 2 element. It is a subtheme to main group organometallic chemistry . [ 2 ] [ 3 ] By far the most common group 2 organometallic compounds are the magnesium-containing Grignard reagents which are widely used in organic chemistry .