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In electrochemistry, cell notation or cell representation is a shorthand method of expressing a reaction in an electrochemical cell.. In cell notation, the two half-cells are described by writing the formula of each individual chemical species involved in the redox reaction across the cell, with all other common ions and inert substances being ignored.
The cation is always named first. Ions can be metals, non-metals or polyatomic ions. Therefore, the name of the metal or positive polyatomic ion is followed by the name of the non-metal or negative polyatomic ion. The positive ion retains its element name whereas for a single non-metal anion the ending is changed to -ide.
Quantities, Units and Symbols in Physical Chemistry, also known as the Green Book, is a compilation of terms and symbols widely used in the field of physical chemistry. It also includes a table of physical constants , tables listing the properties of elementary particles , chemical elements , and nuclides , and information about conversion ...
Since the parent ion can only be 2 P 1/2 or 2 P 3/2, the notation can be shortened to [] or ′ [], where nℓ means the parent ion is in 2 P 3/2 while nℓ′ is for the parent ion in 2 P 1/2 state. Paschen notation is a somewhat odd notation; it is an old notation made to attempt to fit an emission spectrum of neon to a hydrogen-like theory.
A chemical equation is the symbolic representation of a chemical reaction in the form of symbols and chemical formulas.The reactant entities are given on the left-hand side and the product entities are on the right-hand side with a plus sign between the entities in both the reactants and the products, and an arrow that points towards the products to show the direction of the reaction. [1]
An atom (or ion) whose oxidation number increases in a redox reaction is said to be oxidized (and is called a reducing agent). It is accomplished by loss of one or more electrons. The atom whose oxidation number decreases gains (receives) one or more electrons and is said to be reduced. This relation can be remembered by the following mnemonics.
For example, the compound dichlorine hexoxide has an empirical formula ClO 3, and molecular formula Cl 2 O 6, but in liquid or solid forms, this compound is more correctly shown by an ionic condensed formula [ClO 2] + [ClO 4] −, which illustrates that this compound consists of [ClO 2] + ions and [ClO 4] − ions. In such cases, the condensed ...
However when counting electrons, negative ions should have extra electrons placed in their Lewis structures; positive ions should have fewer electrons than an uncharged molecule. When the Lewis structure of an ion is written, the entire structure is placed in brackets, and the charge is written as a superscript on the upper right, outside the ...
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