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The Pinnick oxidation is an organic reaction by which aldehydes can be oxidized into their corresponding carboxylic acids using sodium chlorite (NaClO 2) under mild acidic conditions. It was originally developed by Lindgren and Nilsson. [1] The typical reaction conditions used today were developed by G. A. Kraus.
Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert ... The Pinnick oxidation uses sodium chlorite. [20] References ...
The hydroxy acid first reacts with the 2,2'-Dipyridyldisulfide to form the corresponding 2-pyridinethiol ester, and after a proton transfer, the alkoxide attacks the carbonyl carbon, forming a tetrahedral transition state, before resolving back to the desired lactone and 2-pyridinethione.
Lindgren oxidation is a selective method for oxidizing aldehydes to carboxylic acids. [1] The reaction is named after Bengt O. Lindgren. The oxidation takes place in water containing solvent mixtures under slightly acidic conditions (pH 3–5) with sodium chlorite as oxidizer.
Baeyer–Drewson indigo synthesis; Baeyer–Villiger oxidation, Baeyer–Villiger rearrangement [12]; Bakeland process (Bakelite) Baker–Venkataraman rearrangement, Baker–Venkataraman transformation [13] [14] [15] [16]
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Sarett oxidation; Selenoxide elimination; Shapiro reaction; Sharpless asymmetric dihydroxylation; Epoxidation of allylic alcohols; Sharpless epoxidation; Sharpless oxyamination; Stahl oxidation; Staudinger reaction; Stephen aldehyde synthesis; Swern oxidation
A name reaction (or named reaction) is a chemical reaction named after its discoverer(s) or developer(s). Among the tens of thousands of organic reactions that are known, hundreds of such reactions are typically identified by the eponym. [1]