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Organic redox reactions: the Birch reduction. Organic reductions or organic oxidations or organic redox reactions are redox reactions that take place with organic compounds.In organic chemistry oxidations and reductions are different from ordinary redox reactions, because many reactions carry the name but do not actually involve electron transfer. [1]
Babler-Dauben oxidation of cyclic tertiary allylic alcohols. The reaction produces the desired enone product to high yield (typically >75%), is operationally simple and does not require air-free techniques or heating. [1] It suffers, however, from the very high toxicity and environmental hazard posed by the hexavalent chromium PCC oxidising ...
The Saegusa–Ito oxidation is a chemical reaction used in organic chemistry. It was discovered in 1978 by Takeo Saegusa and Yoshihiko Ito as a method to introduce α-β unsaturation in carbonyl compounds . [ 1 ]
In organic chemistry, the Swern oxidation, named after Daniel Swern, is a chemical reaction whereby a primary or secondary alcohol (−OH) is oxidized to an aldehyde (−CH=O) or ketone (>C=O) using oxalyl chloride, dimethyl sulfoxide (DMSO) and an organic base, such as triethylamine.
The Pinnick oxidation is an organic reaction by which aldehydes can be oxidized into their corresponding carboxylic acids using sodium chlorite (NaClO 2) under mild acidic conditions. It was originally developed by Lindgren and Nilsson. [1] The typical reaction conditions used today were developed by G. A. Kraus.
In organic chemistry, the Hass–Bender oxidation (also called the Hass–Bender carbonyl synthesis [1]) is an organic oxidation reaction that converts benzyl halides into benzaldehydes using the sodium salt of 2-nitropropane as the oxidant. [2] This name reaction is named for Henry B. Hass and Myron L. Bender, who first reported it in 1949. [3]
Saegusa–Ito oxidation; Sakurai reaction; Salol reaction; Sandheimer; Sandmeyer diphenylurea isatin synthesis; Sandmeyer isonitrosoacetanilide isatin synthesis; Sandmeyer reaction; Sanger reagent; Saponification; Sarett oxidation; Schiemann reaction [18] Schiff reaction; Schiff test; Schlenk equilibrium; Schlosser modification; Schlosser ...
The reaction mechanism of Corey–Kim oxidation Under Corey–Kim conditions allylic and benzylic alcohols have a tendency to evolve to the corresponding allyl and benzyl chlorides unless the alcohol activation is very quickly followed by addition of triethylamine .