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It is a partner in Diels–Alder reactions, e.g. with maleic anhydride to give tetrahydrophthalic anhydride. [29] Like other dienes, butadiene is a ligand for low-valent metal complexes, e.g. the derivatives Fe(butadiene)(CO) 3 and Mo(butadiene) 3.
One of the most common way to attach functionality onto a preexisting polymer backbone is through free radical reaction. Free radicals can be formed through plasma , peroxide initiation, etc. [ 3 ] When there is a free radical on the polyolefin chain, maleic anhydride [ 4 ] can be attached to promote further functionalization.
Polybutadiene [butadiene rubber, BR] is a synthetic rubber. It offers high elasticity, high resistance to wear, good strength even without fillers, and excellent abrasion resistance when filled and vulcanized. "Polybutadiene" is a collective name for homopolymers formed from the polymerization of the monomer 1,3-butadiene.
Maleic anhydride is a classic substrate for Diels-Alder reactions. [9] It was used for work in 1928, on the reaction between maleic anhydride and 1,3-butadiene, for which Otto Paul Hermann Diels and Kurt Alder were awarded the Nobel Prize in 1950. It is through this reaction that maleic anhydride is converted to many pesticides and pharmaceuticals.
English: Maleic anhydride - Diels-Alder reaction with 1,3-butadiene. Deutsch: Maleinsäureanhydrid - Diels-Alder-Reaktion mit 1,3-Butadien. Date: 28 January 2019: Source:
Polybutene is an organic polymer made from a mixture of 1-butene, 2-butene, and isobutylene.Ethylene steam cracker C4s are also used as supplemental feed for polybutene. It is similar to polyisobutylene (PIB), which is produced from essentially pure isobutylene made in a C4 complex of a major refinery.
The patent describes the reaction of the alkenes with excess maleic anhydride at 200 °C in an autoclave. The excess alkene is removed by distillation in vacuo, the resulting alkenyl succinic anhydride hydrolyzed with dilute sodium hydroxide solution and the disodium salt reacted with an acid to achieve an alkenebutanedioic acid.
It can be described as the double ester of maleic acid with the alcohol 2-ethylhexanol. It is commonly called dioctyl maleate (DOM), reflecting the older usage of "octane" to refer to any 8-carbon alkane, straight-chained or branched. The compound is manufactured by treating 2-ethylhexanol with maleic anhydride and an