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See the general structure image of an ortho- (or mono-) phosphate ester below on the left, where any of the R groups can be a hydrogen or an organic radical. Di- and tripoly- (or tri-) phosphate esters, etc. are also possible.
General chemical structure of the organophosphate functional group. In organic chemistry, organophosphates (also known as phosphate esters, or OPEs) are a class of organophosphorus compounds with the general structure O=P(OR) 3, a central phosphate molecule with alkyl or aromatic substituents. [1]
It is a phosphate ester-based fluid that is known for its excellent fire resistance and ability to withstand extreme temperature and pressure conditions. It is manufactured by Solutia (now part of Eastman Chemical Company), and formerly manufactured by Monsanto. There are various lines of Skydrol including Skydrol 500B-4, Skydrol LD-4, and ...
Tributyl phosphate, known commonly as TBP, is an organophosphorus compound with the chemical formula (CH 3 CH 2 CH 2 CH 2 O) 3 PO. This colourless, odorless liquid finds some applications as an extractant and a plasticizer. It is an ester of phosphoric acid with n-butanol.
Phosphate esters have the general structure P(=O)(OR) 3 feature P(V). Such species are of technological importance as flame retardant agents, and plasticizers. Lacking a P−C bond, these compounds are in the technical sense not organophosphorus compounds but esters of phosphoric acid. Many derivatives are found in nature, such as ...
Phosphoryl chloride is used on an industrial scale for the manufacture of phosphate esters (organophosphates). These have a wide range of uses, including as flame retardants (bisphenol A diphenyl phosphate, TCPP and tricresyl phosphate), plasticisers for PVC and related polymers (2-ethylhexyl diphenyl phosphate) and hydraulic fluids. [11]
The uranium is then stripped from the DEHPA/kerosene solution with hydrochloric acid, hydrofluoric acid, or carbonate solutions. Sodium carbonate solutions effectively strip uranium from the organic layer, but the sodium salt of DEHPA is somewhat soluble in water, which can lead to loss of the extractant.
Trixylyl phosphate (TXP) is an aromatic phosphate ester. It was historically used as a flame retardant for acetate plastics (cellulose nitrate and cellulose acetate) and PVC. It also saw significant use as a fire-resistant hydraulic fluid. Trixylyl phosphate is now banned or restricted in several jurisdictions, due to its poor safety profile.
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