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The chlor-alkali industry is a major consumer of the world's energy budget. This process converts concentrated sodium chloride solutions into chlorine and sodium hydroxide, which are used to make many other materials and chemicals. The process involves two parallel reactions: 2 Cl − → Cl 2 + 2 e − 2 H 2 O + 2 e − → H 2 + 2 OH −
Even though nitrogen in NCl 3 is bearing a negative charge, the compound is usually called nitrogen trichloride. Chlorination of metals with Cl 2 usually leads to a higher oxidation state than bromination with Br 2 when multiple oxidation states are available, such as in MoCl 5 and MoBr 3. Chlorides can be made by reaction of an element or its ...
Electron capture for almost all non-noble gas atoms involves the release of energy [4] and thus is exothermic. The positive values that are listed in tables of E ea are amounts or magnitudes. It is the word "released" within the definition "energy released" that supplies the negative sign to ΔE.
The adiabatic ionization energy of a molecule is the minimum amount of energy required to remove an electron from a neutral molecule, i.e. the difference between the energy of the vibrational ground state of the neutral species (v" = 0 level) and that of the positive ion (v' = 0). The specific equilibrium geometry of each species does not ...
According to these rules, compounds with the most ionic character will have large positive ions with a low charge, bonded to a small negative ion with a high charge. [25] More generally HSAB theory can be applied, whereby the compounds with the most ionic character are those consisting of hard acids and hard bases: small, highly charged ions ...
Oxidation state is obtained by summing the heteronuclear-bond orders at the atom as positive if that atom is the electropositive partner in a particular bond and as negative if not, and the atom’s formal charge (if any) is added to that sum. The same caveat as above applies.
The geometric mean is approximately equal to the arithmetic mean—which is applied in the first formula above—when the energies are of a similar value, e.g., except for the highly electropositive elements, where there is a larger difference of two dissociation energies; the geometric mean is more accurate and almost always gives positive ...
Similar to a core electron, a valence electron has the ability to absorb or release energy in the form of a photon. An energy gain can trigger the electron to move (jump) to an outer shell; this is known as atomic excitation. Or the electron can even break free from its associated atom's shell; this is ionization to form a positive ion. When an ...