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Glycerol is a good alternative source for butanol production. While glucose sources are valuable and limited, glycerol is abundant and has a low market price because it is a waste product of biodiesel production. Butanol production from glycerol is economically viable using metabolic pathways that exist in the bacterium Clostridium pasteurianum ...
Butanol (also called butyl alcohol) is a four-carbon alcohol with a formula of C 4 H 9 O H, which occurs in five isomeric structures (four structural isomers), from a straight-chain primary alcohol to a branched-chain tertiary alcohol; [1] all are a butyl or isobutyl group linked to a hydroxyl group (sometimes represented as BuOH, sec-BuOH, i-BuOH, and t-BuOH).
The production of butanol by biological means was first performed by Louis Pasteur in 1861. [5] In 1905, Austrian biochemist Franz Schardinger found that acetone could similarly be produced. [ 5 ] In 1910 Auguste Fernbach (1860–1939) developed a bacterial fermentation process using potato starch as a feedstock in the production of butanol.
The main products of syngas fermentation include ethanol, butanol, acetic acid, butyric acid, and methane. [2] Certain industrial processes, such as petroleum refining, steel milling, and methods for producing carbon black, coke, ammonia, and methanol, discharge enormous amounts of waste gases containing mainly CO and H
The largest use of 1-butanol is as an industrial intermediate, particularly for the manufacture of butyl acetate (itself an artificial flavorant and industrial solvent). It is a petrochemical derived from propylene. Estimated production figures for 1997 are: United States 784,000 tonnes; Western Europe 575,000 tonnes; Japan 225,000 tonnes. [8]
The company Energy Environment International developed a method for producing butanol from biomass, which involves the use of two separate micro-organisms in sequence to minimize production of acetone and ethanol byproducts. [12] The Swiss company Butalco GmbH uses a special technology to modify yeasts in order to produce butanol instead of ...
Butyl acetate is commonly manufactured by the Fischer esterification of butanol (or its isomer to make an isomer of butyl acetate) and acetic acid with the presence of sulfuric acid: [7] Butyl acetate is mainly used as a solvent for coatings and inks. [7] It is a component of fingernail polish. [8]
Like other butanols, butan-2-ol has low acute toxicity. The LD 50 is 4400 mg/kg (rat, oral). [6]Several explosions have been reported [7] [8] [9] during the conventional distillation of 2-butanol, apparently due to the buildup of peroxides with the boiling point higher than that of pure alcohol (and therefore concentrating in the still pot during distillation).