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For most crystalline silicon solar cells the change in V OC with temperature is about −0.50%/°C, though the rate for the highest-efficiency crystalline silicon cells is around −0.35%/°C. By way of comparison, the rate for amorphous silicon solar cells is −0.20 to −0.30%/°C, depending on how the cell is made.
Solar powered boats started to become known around 1985 and in 1995 the first commercial solar passenger boats appeared. [41] Solar powered boats have been used successfully at sea. The first crossing of the Atlantic Ocean was achieved in the winter of 2006/2007 by the solar catamaran Sun21. [42] [43] (see also List of solar-powered boats)
The first demonstration of the photovoltaic effect, by Edmond Becquerel in 1839, used an electrochemical cell. He explained his discovery in Comptes rendus de l'Académie des sciences, "the production of an electric current when two plates of platinum or gold immersed in an acid, neutral, or alkaline solution are exposed in an uneven way to solar radiation."
Solar cells operate by absorbing light, exciting the absorber. This creates electron–hole pairs that must be separated into electrons (negative charge carriers) and holes (positive charge carriers) by asymmetry in the solar cell, provided through chemical gradients [4] or electric fields in semiconducting junctions. [5]
Portable solar chargers are used to charge cell phones and other small electronic devices on the go. Chargers on the market today use various types of solar panels, ranging from thin film panels with efficiencies from 7-15% (amorphous silicon around 7%, CIGS closer to 15%), to the slightly more efficient monocrystalline panels which offer efficiencies up to 18%.
Other possible solar cell types are organic solar cells, dye sensitized solar cells, perovskite solar cells, quantum dot solar cells etc. The illuminated side of a solar cell generally has a transparent conducting film for allowing light to enter into the active material and to collect the generated charge carriers.
Charge carriers that recombine cannot be used for photocurrent extraction, therefore for higher solar cell efficiency it is desirable to have a higher effective lifetime. The minority carrier lifetime is also related to the open-circuit voltage of a solar cell, and therefore can be used to infer an implicit current–voltage characteristic of ...
The mostly commonly researched modern photoelectrochemical cell in recent decades has been the Grätzel cell, although much attention has recently shifted away from this topic to perovskite solar cells, due to relatively high efficiency of the latter and the similarity in vapor assisted deposition techniques commonly used in their creation.
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