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R ∗ = 8.314 32 × 10 3 N⋅m⋅kmol −1 ⋅K −1 = 8.314 32 J⋅K −1 ⋅mol −1. Note the use of the kilomole, with the resulting factor of 1000 in the constant. The USSA1976 acknowledges that this value is not consistent with the cited values for the Avogadro constant and the Boltzmann constant. [13]
For example, IUPAC has, since 1982, defined standard reference conditions as being 0 °C and 100 kPa (1 bar), in contrast to its old standard of 0 °C and 101.325 kPa (1 atm). [2] The new value is the mean atmospheric pressure at an altitude of about 112 metres, which is closer to the worldwide median altitude of human habitation (194 m). [10]
The constants listed here are known values of physical constants expressed in SI units; that is, physical quantities that are generally believed to be universal in nature and thus are independent of the unit system in which they are measured. Many of these are redundant, in the sense that they obey a known relationship with other physical ...
The values used for M, g 0, and R * are in accordance with the U.S. Standard Atmosphere, 1976, and the value for R * in particular does not agree with standard values for this constant. [2] The reference value for P b for b = 0 is the defined sea level value, P 0 = 101 325 Pa or 29.92126 inHg.
a (L 2 bar/mol 2) b (L/mol) ; Acetic acid: 17.7098 0.1065 Acetic anhydride: 20.158 0.1263 Acetone: 16.02 0.1124 Acetonitrile: 17.81 0.1168 Acetylene: 4.516 0.0522 Ammonia: 4.225 0.0371
Atmospheric pressure, also known as air pressure or barometric pressure (after the barometer), is the pressure within the atmosphere of Earth.The standard atmosphere (symbol: atm) is a unit of pressure defined as 101,325 Pa (1,013.25 hPa), which is equivalent to 1,013.25 millibars, [1] 760 mm Hg, 29.9212 inches Hg, or 14.696 psi. [2]
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The standard atmosphere was originally defined as the pressure exerted by a 760 mm column of mercury at 0 °C (32 °F) and standard gravity (g n = 9.806 65 m/s 2). [2] It was used as a reference condition for physical and chemical properties, and the definition of the centigrade temperature scale set 100 °C as the boiling point of water at this pressure.