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In supramolecular chemistry, [1] host–guest chemistry describes complexes that are composed of two or more molecules or ions that are held together in unique structural relationships by forces other than those of full covalent bonds. Host–guest chemistry encompasses the idea of molecular recognition and interactions through non-covalent ...
Chemists have long been interested in mimicking chemical processes in nature. Coordination cages quickly became a hot topic as they can be made by self-assembly, a tool of chemistry in nature. [4] The conceptualization of a closed-surface molecule capable of incorporating a guest was described by Donald Cram in 1985. [5]
The black rat is a reservoir host for bubonic plague. The rat fleas that infest the rats are vectors for the disease. In biology and medicine, a host is a larger organism that harbours a smaller organism; [1] whether a parasitic, a mutualistic, or a commensalist guest . The guest is typically provided with nourishment and shelter.
Static molecular recognition is likened to the interaction between a key and a keyhole; it is a 1:1 type complexation reaction between a host molecule and a guest molecule to form a host–guest complex. To achieve advanced static molecular recognition, it is necessary to make recognition sites that are specific for guest molecules.
The reservoir is a porous and permeable lithological unit or set of units that holds the hydrocarbon reserves. Analysis of reservoirs at the simplest level requires an assessment of their porosity (to calculate the volume of in situ hydrocarbons) and their permeability (to calculate how easily hydrocarbons will flow out of them). [ 2 ]
Matrix isolation is an experimental technique used in chemistry and physics. It generally involves a material being trapped within an unreactive matrix. A host matrix is a continuous solid phase in which guest particles (atoms, molecules, ions, etc.) are embedded. The guest is said to be isolated within the host matrix.
They also serve as a reservoir for cholesterol and acyl-glycerols for membrane formation and maintenance. Lipid droplets are found in all eukaryotic organisms and store a large portion of lipids in mammalian adipocytes. Initially, these lipid droplets were considered to merely serve as fat depots, but since the discovery in the 1990s of ...
If the correction factor is greater than one, the reaction displays an asymmetric amplification, also known as a positive non-linear effect. Under the ML 2 model, a (+)-NLE infers a less reactive heterochiral catalyst. In this case, the equilibrium constant K also increases as the correction factor increases.