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Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH 3 CO) 2 O. Commonly abbreviated Ac 2 O , it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis .
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) ... Water: 100.00 0.512 0.00 –1.86 K b & K f [2] Ethyl Acetate: 77.1 [5] Acetic Anhydride: 139.0 [6 ...
Triple point: 289.8 K (16.7 °C), ? Pa Critical point: 593 K (320 °C), 57.8 bar Eutectic point with water –26.7 °C Std enthalpy change of fusionΔ fus H o +11.7 kJ/mol Std entropy change of fusionΔ fus S o: 40.5 J/(mol·K) Std enthalpy change of vaporizationΔ vap H o +23.7 kJ/mol Std entropy change of vaporizationΔ vap S o? J/(mol·K ...
N-Acetylanthranilic acid can be synthesized from 2-bromoacetanilide via palladium-catalyzed carbonylation in tri-n-butylamine-water at 110–130 °C, under 3 atm of carbon monoxide. [4] In the laboratory, it can be easily synthesized from anthranilic acid and acetic anhydride. N-Acetylanthranilic acid exhibits triboluminescence when crushed. [5]
Its half-life in water is approximately 45 min. a 25 °C at 2 < pH < 7. [4] Certain diketenes with two aliphatic chains, such as alkyl ketene dimers (AKDs), are used industrially to improve hydrophobicity in paper. At one time acetic anhydride was prepared by the reaction of ketene with acetic acid: [5]
Melting point: 128.5 °C (263 ... is moderately water ... It can be prepared by the reaction of antimony(III) oxide with acetic anhydride: Sb 2 O 3 + 3 C 4 H 6 O 3 ...
Melting point: −23 °C (−9 °F; 250 K) ... 40% ethanol/water: 30: 9.8 70% dioxane/water: 28: ... Acetone and acetic anhydride ...