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Chlorophyll b is made by the same enzyme acting on chlorophyllide b. The same is known for chlorophyll d and f, both made from corresponding chlorophyllides ultimately made from chlorophyllide a. [39] In Angiosperm plants, the later steps in the biosynthetic pathway are light-dependent. Such plants are pale if grown in darkness.
However, when porphyrin-based photoautotrophs evolved and started to photosynthesize, which included both the primitive purple bacteria using bacteriochlorophyll and cyanobacteria using chlorophyll, highly reactive dioxygen was released as a byproduct of water splitting and started to accumulate, first in the ocean and then in the atmosphere.
These organisms perform photosynthesis through organelles called chloroplasts and are believed to have originated about 2 billion years ago. [1] Comparing the genes of chloroplast and cyanobacteria strongly suggests that chloroplasts evolved as a result of endosymbiosis with cyanobacteria that gradually lost the genes required to be free-living.
P680 + is the strongest biological oxidizing agent known, with an estimated redox potential of ~1.3 V. [3] This makes it possible to oxidize water during oxygenic photosynthesis. P680 + recovers its lost electron by oxidizing water via the oxygen-evolving complex , which regenerates P680.
Chlorophyll a, b, and d. Chlorophyll synthase [14] completes the biosynthesis of chlorophyll a by catalysing the reaction EC 2.5.1.62. chlorophyllide a + phytyl diphosphate chlorophyll a + diphosphate. This forms an ester of the carboxylic acid group in chlorophyllide a with the 20-carbon diterpene alcohol phytol.
The antenna pigments are predominantly chlorophyll b, xanthophylls, and carotenes. Chlorophyll a is known as the core pigment. Their absorption spectra are non-overlapping and broaden the range of light that can be absorbed in photosynthesis. The carotenoids have another role as an antioxidant to prevent photo-oxidative damage of chlorophyll ...
The process of photosynthesis was discovered by Jan Ingenhousz, a Dutch-born British physician and scientist, first publishing about it in 1779. [ 1 ] The first photosynthetic organisms probably evolved early in the evolutionary history of life and most likely used reducing agents such as hydrogen rather than water. [ 2 ]
Chlorophyll does not reflect light but chlorophyll-containing tissues appear green because green light is diffusively reflected by structures like cell walls. [4] This photosynthetic pigment is essential for photosynthesis in eukaryotes, cyanobacteria and prochlorophytes because of its role as primary electron donor in the electron transport ...