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The creation of sparks from metals is based on the pyrophoricity of small metal particles, and pyrophoric alloys are made for this purpose. [2] Practical applications include the sparking mechanisms in lighters and various toys, using ferrocerium; starting fires without matches, using a firesteel; the flintlock mechanism in firearms; and spark testing ferrous metals.
Division 4.2: Spontaneously Combustible . Spontaneously combustible material is: Pyrophoric Material: A pyrophoric material is a liquid or solid that, even in small quantities and without an external ignition source, can ignite within five (5) minutes after coming in contact with air when tested according to the UN Manual of Tests and Criteria.
A flammable liquid is a liquid which can be easily ignited in air at ambient temperatures, i.e. it has a flash point at or below nominal threshold temperatures defined by a number of national and international standards organisations.
Pyrophoric liquids are liable to ignite after 5 minutes of coming in contact with air. Pyrophoric solids follow the same criteria as pyrophoric liquids. Self-heating substances, which differ from self-reactive substances in that they will only ignite in large quantities (kilograms) and after a long duration of time (hours or days).
The GHS transport pictograms are the same as those recommended in the UN Recommendations on the Transport of Dangerous Goods, widely implemented in national regulations such as the U.S. Federal Hazardous Materials Transportation Act (49 U.S.C. 5101–5128) and D.O.T. regulations at 49 C.F.R. 100–185.
The NA numbers (North American Numbers are assigned by the United States Department of Transportation, supplementing the larger set of UN numbers, for identifying hazardous materials. NA numbers largely duplicate UN numbers, however a selection of additional numbers are provided for materials that are not covered by UN numbers as a hazardous ...
UN Number Class Proper Shipping Name UN 3101: 5.2: Organic peroxide type B, liquid : UN 3102: 5.2: Organic peroxide type B, solid UN 3103: 5.2: Organic peroxide type C, liquid
Group L: Explosive substance or article containing an explosive substance and presenting a special risk (e.g., due to water-activation or presence of hybergolic liquids, phosphides or pyrophoric substances) needing isolation of each type. Group N: Articles predominantly containing extremely insensitive substances.