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Xylyl bromide, CN and CS are the oldest of these agents. CS is the most widely used. CN has the most recorded toxicity. [3] Typical manufacturer warnings on tear gas cartridges state "Danger: Do not fire directly at person(s). Severe injury or death may result." [27] Tear gas guns do not have a manual setting to adjust the range of fire. The ...
Xylyl bromide is an irritant and lachrymatory agent.It has been incorporated in chemical weapons since the early months of World War I.Some commentators say the first use was in August 1914, when the French attacked German soldiers with tear gas grenades, [2] [3] but the agent used in that incident was more likely to be ethyl bromoacetate, which the French had tested before the war.
Cyanogen is typically generated from cyanide compounds. One laboratory method entails thermal decomposition of mercuric cyanide: . 2 Hg(CN) 2 → (CN) 2 + Hg 2 (CN) 2 Or, one can combine solutions of copper(II) salts (such as copper(II) sulfate) with cyanides; an unstable copper(II) cyanide is formed which rapidly decomposes into copper(I) cyanide and cyanogen.
Cyanogen bromide is the inorganic compound with the formula (CN)Br or BrCN. It is a colorless solid that is widely used to modify biopolymers, fragment proteins and peptides (cuts the C-terminus of methionine), and synthesize other compounds. The compound is classified as a pseudohalogen.
The compound 2-chlorobenzalmalononitrile (also called o-chlorobenzylidene malononitrile; chemical formula: C 10 H 5 ClN 2), a cyanocarbon, is the defining component of the lachrymatory agent commonly referred to as CS gas, a tear gas which is used as a riot control agent, and is banned for use in warfare due to the 1925 Geneva Protocol.
White Cross (Weiẞkreuz) is a World War I chemical warfare agent consisting of one or more lachrymatory agents: bromoacetone (BA), bromobenzyl cyanide (Camite), bromomethyl ethyl ketone (homomartonite, Bn-stoff), chloroacetone (Tonite, A-stoff), ethyl bromoacetate, and/or xylyl bromide.
Being benzylic and hence weakened, the C–H bonds of the methyl groups are susceptible to free-radical reactions, including halogenation to the corresponding xylene dichlorides (bis(chloromethyl)benzenes), while mono-bromination yields xylyl bromide, a tear gas agent.
A chemical weapon agent (CWA), or chemical warfare agent, is a chemical substance whose toxic properties are meant to kill, injure or incapacitate human beings.About 70 different chemicals have been used or stockpiled as chemical weapon agents during the 20th century, although the Organisation for the Prohibition of Chemical Weapons (OPCW) has an online database listing 35,942 chemicals which ...